Dr. Mónica H. Pérez-Temprano

Catalysis

Group Leader:

Mónica H. Pérez –Temprano

Administrative Support: 

Núria Planella

Postdoctoral Researchers:

Alessandra Casnati

PhD Students:

Sara López Resano / Jiayu Zhang / Sergio Barranco Raflus / Burak Ates Ceresuela

Summary

The group of Dr. Pérez-Temprano is focused on the development of new synthetic catalytic methods with cobalt through detailed knowledge of the catalytic process. To develop their research projects, they apply different approaches, from synthetic organic chemistry to mechanical studies, including the capture of highly reactive reaction intermediates.

Publications

Engineering a mild and site-selective Ru-catalyzed C(sp2)–H alkylation protocol
Pérez-Temprano, M. H.
Chem Catalysis 20211 (3), 497-499

Redefining the Mechanistic Scenario of Carbon–Sulfur Nucleophilic Coupling via High‐Valent Cp*Co(IV) Species
López-Resano, S.; Martínez de Salinas, S.; Garcés-Pineda, F. A.; Moneo-Corcuera, A.; Galán-Mascarós, J. R.; Maseras, F.; Perez-Temprano, M. H.
Angew. Chem. Int. Ed. 202160 (20), 11217-11221

 

Projects

MD3dCAT
Mechanism-driven Design of 3d Transition Metal Catalyzed CH Functionalization Reactions
Ministerio de Ciencia e Innovación | Ref: PID2020-112733GB-100

COBIST
Alternatives to Traditional Cross-Coupling Reactions to promote C-C Bond Formation: Investigation of Bimetallic Systems and Cobalt Catalysis
Ministerio | Ref: CTQ2016-79942-P

ICIQ-Starting Career Programme
Ministerio, Severo Ochoa | Ref: ICIQ-SCP

 

Features

High-valent Cp*Co(IV) in C-H functionalization reactions revealed
https://www.iciq.org/high-valent-cpcoiv-in-c-h-functionalization-reactions-revealed/